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56579-01 - Lecture: Stereoselective Organic Synthesis (3 CP)
| Semester | spring semester 2025 |
| Course frequency | Irregular |
| Lecturers |
Andreas Pfaltz (andreas.pfaltz@unibas.ch)
Christof Sparr (christof.sparr@unibas.ch, Assessor) |
| Content | Conformational Analysis, Diastereoselective Synthesis, Chiral Auxiliaries and Reagents, Catalytic Stereoselective Hydrogenation, Stereoselective Carbonyl Addition, Autocatalysis & NLEs, Catalytic Cycloadditions and Rearrangements, Stereoselective Amine and NHC-Catalysis, Catalytic Stereoselective Oxidations, Stereoselective Allylic Alkylations, Catalytic meso-Desymmetrisations, Resolution & DKR, Stereoselective Olefinations, Enantioselective Metathesis and Atroposelective Catalysis |
| Learning objectives | General principles of stereoselective synthesis, Stereoselective catalysis, Selectivity-determining intra- and intermolecular interactions in competing transitions states, Critical evaluation of common selectivity models, Application of stereoselective synthesis. |
| Bibliography | • E. M. Carreira, L. Kvaerno, Classics in Stereoselective Synthesis, 1st Edition, Wiley-VCH, Weinheim, 2009. • Asymmetric Synthesis - The Essentials, 2nd Edition (Eds.: M. Christmann, S. Bräse), Wiley-VCH, Weinheim, 2008; Asymmetric Synthesis II, 1st Edition, (Eds.: M. Christmann, S. Bräse), Wiley-VCH, Weinheim, 2012. |
| Admission requirements | Basic knowledge of stereoselective organic synthesis (e.g. from OC II 11034) |
| Course application | https://services.unibas.ch |
| Language of instruction | English |
| Use of digital media | No specific media used |
| Interval | Weekday | Time | Room |
|---|---|---|---|
| wöchentlich | Tuesday | 09.15-12.00 | Chemie, Organische, Kleiner Hörsaal OC |
Dates
| Modules |
Doctorate Chemistry: Recommendations (PhD subject: Chemistry) Module Specialisation: Chemistry (Master's Studies: Nanosciences) Module: Organic Chemistry (Master's Studies: Chemistry) |
| Assessment format | continuous assessment |
| Assessment details | Oral exam |
| Assessment registration/deregistration | Reg.: course registration, dereg: cancel course registration |
| Repeat examination | no repeat examination |
| Scale | 1-6 0,5 |
| Repeated registration | as often as necessary |
| Responsible faculty | Faculty of Science, studiendekanat-philnat@unibas.ch |
| Offered by | Departement Chemie |